Sir Henry Raeburn PRSAPortrait of Commander Hugh Clapperton (1788-1827), c. 1817- Sir Henry Raeburn PRSAPortrait of Elizabeth Campbell, Marchesa di Spineto, c. 1812
- Sir Henry Raeburn PRSAPortrait of an Officer, c. 1810
- Sir Henry Raeburn PRSAPortrait of John Campbell of Kilberry (1780-1838), c. 1815
- Sir Henry Raeburn PRSAPortrait of Margaret Anne Forbes-Drummond, Lady Walker Drummond (d. 1876), c. 1810
- Sir Henry Raeburn PRSAPortrait of Isabella Halkett, c. 1795
- Harold RathbonePortrait of Mathilde Blind (1841-96), 1880s
- Charles Paul RenouardLord Randolph Churchill on the Front Bench, 1886
- Charles Paul RenouardPortrait Sketch of Charles Stewart Parnell, 1886
- Charles Paul RenouardPortrait of Joseph Chamberlain (1836-1914), 1870s
- Circle of Sir Joshua Reynolds PRAStrawberry Girl, c. 1810
- William Birnie Rhind RSABust of R.Gascoyne-Cecil, 3rd Marquess of Salisbury (1830-1918), 1894
- Andrew RobertsonPortrait miniature of a ‘J. Jenkyn’, 1819
- Charles RobertsonPortrait of a John Robert Hopper (b. c. 1799-1863), aged nineteen, early 18th century
- Sampson Towgood Roch(e)Portrait miniature of two brothers embracing, one holding a book, early 19th century
- Francois Theodore RochardPortrait miniature of the artist’s daughter, Eugenie Rochard (b. 1814), as Psyche, mid 19th century
- William Thomas RodenPortrait of William Ewart Gladstone PM (1808-98), 1877
- Richard RothwellPortrait of Rt. Hon. William Huskinsson (1770-1830), c. 1820
- Russian SchoolPrince Vasily Sergeevich Golitsyn (1792-1856) wearing a blue coat and a ribbon of the Royal Swedish Order of the Sword, Knight Class, c. 1825
- William SalterThe Waterloo Banquet, 1836
- Frederick SayPortrait of Jocelyn 3rd Earl of Roden, c. 1830
- Scottish SchoolPortrait miniature of an architect, possibly James Craig (1739-95), seated in a room with a copy of ‘Palladio’, an architectural plan on the wall behind, c. 1770
- Charles ShirreffAn Officer, wearing the uniform of the 34th (Cumberland) Regiment of Foot, his scarlet coat with yellow facings, silver epaulette and cross belt with regimental badge, 1803
- Louis-Marie SicardiPortrait of young woman in bust with a décolleté blue corsage covered with a scarf of gauze, a silk ribbon holding her hair
- John SimpsonErnest II, Duke of Saxe-Coburg and Gotha (1818-1893), wearing uniform, Major-General of the Royal Saxonian Garde-Reiter Regiment, 1845
- John SmartPortrait drawing of John Dighton (1793-1810), wearing blue jacket with brass buttons over yellow waistcoat and white cravat, the portrait set into a drawn surround, 1810
- John SmartA young man of the Finch-Hatton family, wearing a navy coat and white waistcoat, 1811
- Colvin Smith RSAPortrait of Francis Lord Jeffrey (1773-1850), 1820s
- John Raphael SmithPortrait of the Whig Statesman Charles James Fox (1749-1806), 1802
- Anthony StewartPortrait miniature of Hungerford Crewe (1812-94), 3rd Baron Crewe dressed in white smock with blue ribbon tied at the waist
- Jane StuartPortrait of George Washington (1732-99), c. 1820
- Jane StuartPortrait of George Washington, 1840s
- Samuel John StumpPortrait of an Actor, 1780s
- Thomas SullyThe Howell Brothers, c. 1840
- Thomas SullyPeasant Girl, 1857
- Thomas SullySelf Portrait, 1828
- Edward TaylerThree portraits of children of the Danish Royal Family, late 19th century
- J. Havard ThomasPortrait Bust of Cardinal-Archbishop Henry Edward Manning (1808-92), 1886
- Circle of Bertel (Albert) ThorvaldsenPortrait Bust of George Gordon (1788-1824), 6th Lord Byron, 1817
- Peter TurnerelliPortrait bust of George III (1738-1820), 1812
- George Watson PRSARobert Grant (1799-1820), c. 1820
- John Dawson WatsonPortrait of the artist Paul Falconer Poole (1807-79), 1870s
- John Watson-Gordon PRSA, RAPortrait of Sir Walter Scott, c. 1830
- George Frederic Watts OM, RAPortrait of Giuseppe Garibaldi (1802-82), 1864
- George Frederic Watts OM, RAPortrait of Miss May Wedderburn, 1880s
- Attributed to Henry WeigallPortrait bust of Arthur Wellesley, 1st Duke of Wellington (1769-1852)
- John Richard WildmanPortrait of Arthur Wellesley (1769-1852), 1st Duke of Wellington KG PM, 1830s
- David WilkiePortrait of Captain Rammage RN, probably Edward Ramage (?b. 1766/7), c. 1805/6
- David Wilkie RAPortrait of King William IV (1765-1837), Three-Quarter Length, Wearing the Robes of the Garter, c. 1831
- After Franz Xaver WinterhalterPortrait of Queen Victoria (1819-1901), 1840s
- After Franz Xaver WinterhalterPortrait of the young Queen Victoria (1819-1901), 1860s
- After Franz Xaver WinterhalterPortrait of Queen Victoria (1819-1901), 1846
- Studio of Franz Xaver WinterhalterPortrait of Prince Albert Prince Consort (1819-61), c. 1860
- Studio of Franz Xaver WinterhalterPortrait of Queen Victoria (1819-1901), mid 19th century
- Studio of Franz Xaver WinterhalterPortrait of Prince Albert Prince Consort (1819-61), c. 1860
- William WoodPortrait of a Lady, c. 1800
- William WoodPortrait miniature of Captain Jonathan Birch, wearing blue coat and white waistcoat, 1805
- John WrightPortrait of Charles, 2nd Earl Grey (1764-1845), 1811
- John Inigo WrightJohn Julius Angerstein (1735-1823), wearing brown fur-lined robe, black coat and white chemise, c. 1816-19
- Henry WyattSelf-Portrait, 1826
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